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Electrochemical Investigations of Sydnone Derivatives at Glassy Carbon Electrode

B. S. Sherigara
Y. Shivaraj
Ronald J. Mascarenhas
Satheesh Rainoji
Balakrishna Kalluraya

Puni tekst: engleski, pdf (176 KB) str. 273-279 preuzimanja: 869* citiraj
APA 6th Edition
Sherigara, B.S., Shivaraj, Y., Mascarenhas, R.J., Rainoji, S. i Kalluraya, B. (2006). Electrochemical Investigations of Sydnone Derivatives at Glassy Carbon Electrode. Croatica Chemica Acta, 79 (2), 273-279. Preuzeto s https://hrcak.srce.hr/4158
MLA 8th Edition
Sherigara, B. S., et al. "Electrochemical Investigations of Sydnone Derivatives at Glassy Carbon Electrode." Croatica Chemica Acta, vol. 79, br. 2, 2006, str. 273-279. https://hrcak.srce.hr/4158. Citirano 07.04.2020.
Chicago 17th Edition
Sherigara, B. S., Y. Shivaraj, Ronald J. Mascarenhas, Satheesh Rainoji i Balakrishna Kalluraya. "Electrochemical Investigations of Sydnone Derivatives at Glassy Carbon Electrode." Croatica Chemica Acta 79, br. 2 (2006): 273-279. https://hrcak.srce.hr/4158
Harvard
Sherigara, B.S., et al. (2006). 'Electrochemical Investigations of Sydnone Derivatives at Glassy Carbon Electrode', Croatica Chemica Acta, 79(2), str. 273-279. Preuzeto s: https://hrcak.srce.hr/4158 (Datum pristupa: 07.04.2020.)
Vancouver
Sherigara BS, Shivaraj Y, Mascarenhas RJ, Rainoji S, Kalluraya B. Electrochemical Investigations of Sydnone Derivatives at Glassy Carbon Electrode. Croatica Chemica Acta [Internet]. 2006 [pristupljeno 07.04.2020.];79(2):273-279. Dostupno na: https://hrcak.srce.hr/4158
IEEE
B.S. Sherigara, Y. Shivaraj, R.J. Mascarenhas, S. Rainoji i B. Kalluraya, "Electrochemical Investigations of Sydnone Derivatives at Glassy Carbon Electrode", Croatica Chemica Acta, vol.79, br. 2, str. 273-279, 2006. [Online]. Dostupno na: https://hrcak.srce.hr/4158. [Citirano: 07.04.2020.]

Sažetak
Electrochemical reduction of the –N=N– moiety of sydnone derivatives, like 3-phenyl sydnone, tolyl sydnone and anisyl sydnone, was studied using cyclic voltammetry at a glassy carbon electrode. In acid medium, the above compounds were found to show irreversible electrochemical charge transfer in the pH range studied. Electrochemical studies of these sydnones were carried out in partially aqueous media containing organic co-solvents such as acetonitrile, dimethylformamide, methanol and dimethylsulphoxide. Physical parameters such as the charge transfer coefficient and diffusion coefficient, as well as the effects of variation of the electroactive species concentration, sweep rate, organic solvents, and pH on peak parameters were studied. The reduced products were characterized by IR, NMR and mass spectral studies. The
effect of surfactants on the electrochemical reduction of 3-phenyl sydnone was studied using cationic, anionic and non-ionic surfactants.

Ključne riječi
voltammetry; reduction; sydnone; glassy carbon electrode; surfactants

Hrčak ID: 4158

URI
https://hrcak.srce.hr/4158

Posjeta: 1.112 *