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Croatica Chemica Acta, Vol. 76 No. 3, 2003.

Izvorni znanstveni članak

A Model of CE Mechanism on Spherical Electrodes

Milivoj Lovrić ; Center for Marine and Environmental Research, Ruđer Bošković Institute, P.O. Box 180, Zagreb 10002, Croatia
Yakov I. Tur'yan ; The National Physical Laboratory of Israel, Danciger »A« Bldg, Givat Ram, 91904 Jerusalem, Israel

Puni tekst: engleski, pdf (128 KB) str. 189-197 preuzimanja: 318* citiraj
APA 6th Edition
Lovrić, M. i Tur'yan, Y.I. (2003). A Model of CE Mechanism on Spherical Electrodes. Croatica Chemica Acta, 76 (3), 189-197. Preuzeto s https://hrcak.srce.hr/103168
MLA 8th Edition
Lovrić, Milivoj i Yakov I. Tur'yan. "A Model of CE Mechanism on Spherical Electrodes." Croatica Chemica Acta, vol. 76, br. 3, 2003, str. 189-197. https://hrcak.srce.hr/103168. Citirano 23.04.2021.
Chicago 17th Edition
Lovrić, Milivoj i Yakov I. Tur'yan. "A Model of CE Mechanism on Spherical Electrodes." Croatica Chemica Acta 76, br. 3 (2003): 189-197. https://hrcak.srce.hr/103168
Harvard
Lovrić, M., i Tur'yan, Y.I. (2003). 'A Model of CE Mechanism on Spherical Electrodes', Croatica Chemica Acta, 76(3), str. 189-197. Preuzeto s: https://hrcak.srce.hr/103168 (Datum pristupa: 23.04.2021.)
Vancouver
Lovrić M, Tur'yan YI. A Model of CE Mechanism on Spherical Electrodes. Croatica Chemica Acta [Internet]. 2003 [pristupljeno 23.04.2021.];76(3):189-197. Dostupno na: https://hrcak.srce.hr/103168
IEEE
M. Lovrić i Y.I. Tur'yan, "A Model of CE Mechanism on Spherical Electrodes", Croatica Chemica Acta, vol.76, br. 3, str. 189-197, 2003. [Online]. Dostupno na: https://hrcak.srce.hr/103168. [Citirano: 23.04.2021.]

Sažetak
A model of electrode reaction preceded by a first-order chemical reaction under chronoamperometric conditions on spherical electrodes has been developed. A general solution applying to all values of equilibrium constants, including very small ones, was obtained by numerical integration. Well-known analytical solutions for steady-state and near-steady-state conditions and for pure kinetic currents were shown to be special cases of the general solution. The conditions for their application are given.

Ključne riječi
CE mechanism; chronoamperometry; spherical electrodes; microelectrodes

Hrčak ID: 103168

URI
https://hrcak.srce.hr/103168

Posjeta: 497 *