Izvorni znanstveni članak

https://doi.org/10.5562/cca2443

Photoisomerization and Photocyclization of 5-Styryloxazole

Ivana Šagud ; Department of Organic Chemistry, Faculty of Chemical Engineering and Technology, University of Zagreb, Marulićev trg 19, HR-10000 Zagreb, Croatia
Marija Šindler-Kulyk ; Department of Organic Chemistry, Faculty of Chemical Engineering and Technology, University of Zagreb, Marulićev trg 19, HR-10000 Zagreb, Croatia
Anna Spalletti ; Department of Chemistry, Biology and Biotechnologies and Centro di Eccellenza Materiali Innovativi Nanostrutturati (CEMIN), University of Perugia, Piazza Università 1, 06123 Perugia, Italy
Ugo Mazzucato ; Department of Chemistry, Biology and Biotechnologies and Centro di Eccellenza Materiali Innovativi Nanostrutturati (CEMIN), University of Perugia, Piazza Università 1, 06123 Perugia, Italy

Sažetak

This paper describes the competition of the relaxation processes (fluorescence, isomerization and cyclization) of 5-styryloxazole in the first excited singlet state. The study is carried out under mild conditions and in the first stage of irradiation to compare the photobehaviour with that reported in a previous work on preparative scale. The quantum yields of the radiative and reactive deactivation are compared with those of the analogous compounds containing pentatomic heteroaryl groups.

Ključne riječi

electrocyclization; fluorescence; oxazoles; photochemistry

Hrčak ID:

131525

URI

https://hrcak.srce.hr/131525

Datum izdavanja:

22.12.2014.

Posjeta: 2.007 *