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Kratko priopćenje
https://doi.org/10.5562/cca2438

UV Photoelectron Spectroscopy and Outer Valence Electronic Structure of Dihalobenzenes

Igor Novak   ORCID icon orcid.org/0000-0002-3413-2605 ; Charles Sturt University, POB 883, Orange NSW 2800, Australia
Leo Klasinc ; Ruđer Bošković Institute, Bijenička cesta 54, HR-10000 Zagreb, Croatia;Louisiana State University, Baton Rouge LA 70803, USA
Boris Šket ; University of Ljubljana, SI-1000 Ljubljana, Slovenia
Delano P. Chong ; University of British Columbia, Vancouver, B.C. Canada V6T 1Z1
Sean P. McGlynn ; Louisiana State University, Baton Rouge LA 70803, USA

Puni tekst: engleski, pdf (1 MB) str. 495-499 preuzimanja: 549* citiraj
APA 6th Edition
Novak, I., Klasinc, L., Šket, B., Chong, D.P. i McGlynn, S.P. (2014). UV Photoelectron Spectroscopy and Outer Valence Electronic Structure of Dihalobenzenes. Croatica Chemica Acta, 87 (4), 495-499. https://doi.org/10.5562/cca2438
MLA 8th Edition
Novak, Igor, et al. "UV Photoelectron Spectroscopy and Outer Valence Electronic Structure of Dihalobenzenes." Croatica Chemica Acta, vol. 87, br. 4, 2014, str. 495-499. https://doi.org/10.5562/cca2438. Citirano 20.10.2019.
Chicago 17th Edition
Novak, Igor, Leo Klasinc, Boris Šket, Delano P. Chong i Sean P. McGlynn. "UV Photoelectron Spectroscopy and Outer Valence Electronic Structure of Dihalobenzenes." Croatica Chemica Acta 87, br. 4 (2014): 495-499. https://doi.org/10.5562/cca2438
Harvard
Novak, I., et al. (2014). 'UV Photoelectron Spectroscopy and Outer Valence Electronic Structure of Dihalobenzenes', Croatica Chemica Acta, 87(4), str. 495-499. https://doi.org/10.5562/cca2438
Vancouver
Novak I, Klasinc L, Šket B, Chong DP, McGlynn SP. UV Photoelectron Spectroscopy and Outer Valence Electronic Structure of Dihalobenzenes. Croatica Chemica Acta [Internet]. 2014 [pristupljeno 20.10.2019.];87(4):495-499. https://doi.org/10.5562/cca2438
IEEE
I. Novak, L. Klasinc, B. Šket, D.P. Chong i S.P. McGlynn, "UV Photoelectron Spectroscopy and Outer Valence Electronic Structure of Dihalobenzenes", Croatica Chemica Acta, vol.87, br. 4, str. 495-499, 2014. [Online]. https://doi.org/10.5562/cca2438

Sažetak
The electronic structures of nine dihalobenzenes (C6H4FX; X = Cl, Br, I) have been studied by UV photoelectron spectroscopy (UPS) and assigned by comparison with the reported spectra of monoha-lobenzenes (C6H5X; X = Cl, Br, I). and quantum chemical calculations. Our results show that the fluorine substituent modifies energies of π- and halogen lone pair orbitals to a significant degree depending on its location (topology). We also demonstrate that the inductive effect of fluorine atom on the benzene ring can be readily observed and interpreted.

Ključne riječi
halobenzenes; inductive effect; resonance effect

Hrčak ID: 131551

URI
https://hrcak.srce.hr/131551

Posjeta: 787 *