Croatica Chemica Acta, Vol. 71 No. 1, 1998.
Prethodno priopćenje
Possible High Tc Superconductivity in Ag Doped PbO1+δ (0.4 < δ < 0.6)
Danijel Djurek
; A. Volta Applied Ceramics (AVAC), Kesten brijeg 5, 10000 Zagreb, Croatia
Zvonko Medunić
; A. Volta Applied Ceramics (AVAC), Kesten brijeg 5, 10000 Zagreb, Croatia
Anton Tonejc
; Faculty of Science, Physics Dept., Bijenička c. 32, 10001 Zagreb, Croatia
Matija Paljević
; Ruđer Bošković Institute, Bijenička c. 54, 10001 Zagreb, Croatia
Sažetak
We have found that the doping of Pb3O4 with silver and its treatment in elevated oxygen pressure result in a number of novel metallic phases. The Pb1-xAgxO1+δ phases (0.4 < δ < 0.6; x ≈ 0.1-0.15) prepared at 260-330 °C exhibit electric and magnetic properties compatible with the indication of superconductivity (SC), which appears at Tc ≈ 285 K. SC can be attributed to Ag doped lead sesquioxide Pb2-xAgxO3-y (y ≈ ±0.2).
Ključne riječi
Hrčak ID:
132326
URI
Datum izdavanja:
2.3.1998.
Posjeta: 1.229 *