Synthesis and Characterisation of [Pd10(μ-CO)(μ3-CO)4(PEt3)6] and [Pd10(μ-CO)6(μ3-CO)2(μ-CNXylyl)2(PEt3)6]
D. Michael P. Mingos
; Chemistry Department, Imperial College of Science, Technology and Medicine, South Kensington, London SW7 2AY, United Kingdom
Christopher M. Hill
; Chemistry Department, Imperial College of Science, Technology and Medicine, South Kensington, London SW7 2AY, United Kingdom
APA 6th Edition Mingos, D.M.P. i Hill, C.M. (1995). Synthesis and Characterisation of [Pd10(μ-CO)(μ3-CO)4(PEt3)6] and [Pd10(μ-CO)6(μ3-CO)2(μ-CNXylyl)2(PEt3)6]. Croatica Chemica Acta, 68 (4), 745-767. Preuzeto s https://hrcak.srce.hr/136691
MLA 8th Edition Mingos, D. Michael P. i Christopher M. Hill. "Synthesis and Characterisation of [Pd10(μ-CO)(μ3-CO)4(PEt3)6] and [Pd10(μ-CO)6(μ3-CO)2(μ-CNXylyl)2(PEt3)6]." Croatica Chemica Acta, vol. 68, br. 4, 1995, str. 745-767. https://hrcak.srce.hr/136691. Citirano 21.04.2021.
Chicago 17th Edition Mingos, D. Michael P. i Christopher M. Hill. "Synthesis and Characterisation of [Pd10(μ-CO)(μ3-CO)4(PEt3)6] and [Pd10(μ-CO)6(μ3-CO)2(μ-CNXylyl)2(PEt3)6]." Croatica Chemica Acta 68, br. 4 (1995): 745-767. https://hrcak.srce.hr/136691
Harvard Mingos, D.M.P., i Hill, C.M. (1995). 'Synthesis and Characterisation of [Pd10(μ-CO)(μ3-CO)4(PEt3)6] and [Pd10(μ-CO)6(μ3-CO)2(μ-CNXylyl)2(PEt3)6]', Croatica Chemica Acta, 68(4), str. 745-767. Preuzeto s: https://hrcak.srce.hr/136691 (Datum pristupa: 21.04.2021.)
Vancouver Mingos DMP, Hill CM. Synthesis and Characterisation of [Pd10(μ-CO)(μ3-CO)4(PEt3)6] and [Pd10(μ-CO)6(μ3-CO)2(μ-CNXylyl)2(PEt3)6]. Croatica Chemica Acta [Internet]. 1995 [pristupljeno 21.04.2021.];68(4):745-767. Dostupno na: https://hrcak.srce.hr/136691
IEEE D.M.P. Mingos i C.M. Hill, "Synthesis and Characterisation of [Pd10(μ-CO)(μ3-CO)4(PEt3)6] and [Pd10(μ-CO)6(μ3-CO)2(μ-CNXylyl)2(PEt3)6]", Croatica Chemica Acta, vol.68, br. 4, str. 745-767, 1995. [Online]. Dostupno na: https://hrcak.srce.hr/136691. [Citirano: 21.04.2021.]
Sažetak The decanuclear palladium cluster compounds [Pdio(u-CO)g(^3-CO)4 (PEtglg] and [Pdio(/(-CO)g(ii3-CO)2(//-CNXyl)2(PEt3)g] (Xyl = CgH^M^- 2,6) have been synthesised and characterised by a combination of spectroscopic data and single crystal X-ray crystallographic analyses. The former has a distorted tetracapped octahedral skeletal geometry and the latter a hexacapped tetrahedral geometry. The latter is unique in cluster chemistry and the structural change induced by the addition of isocyanide represents an interesting example of the effect of the steric requirements of the isocyanide ligand influencing the total electron count and geometry of the cluster. [Pdio(/<-CO)8(/i3-CO)4(PEt3)g] reacts with SO2 to give [Pd5(/(-S02)2(p3-S02)2(PEt3)5].