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Synthesis and Characterisation of [Pd10(μ-CO)(μ3-CO)4(PEt3)6] and [Pd10(μ-CO)63-CO)2(μ-CNXylyl)2(PEt3)6]

D. Michael P. Mingos ; Chemistry Department, Imperial College of Science, Technology and Medicine, South Kensington, London SW7 2AY, United Kingdom
Christopher M. Hill ; Chemistry Department, Imperial College of Science, Technology and Medicine, South Kensington, London SW7 2AY, United Kingdom

Puni tekst: engleski, pdf (7 MB) str. 745-767 preuzimanja: 177* citiraj
APA 6th Edition
Mingos, D.M.P. i Hill, C.M. (1995). Synthesis and Characterisation of [Pd10(μ-CO)(μ3-CO)4(PEt3)6] and [Pd10(μ-CO)63-CO)2(μ-CNXylyl)2(PEt3)6]. Croatica Chemica Acta, 68 (4), 745-767. Preuzeto s https://hrcak.srce.hr/136691
MLA 8th Edition
Mingos, D. Michael P. i Christopher M. Hill. "Synthesis and Characterisation of [Pd10(μ-CO)(μ3-CO)4(PEt3)6] and [Pd10(μ-CO)63-CO)2(μ-CNXylyl)2(PEt3)6]." Croatica Chemica Acta, vol. 68, br. 4, 1995, str. 745-767. https://hrcak.srce.hr/136691. Citirano 21.04.2021.
Chicago 17th Edition
Mingos, D. Michael P. i Christopher M. Hill. "Synthesis and Characterisation of [Pd10(μ-CO)(μ3-CO)4(PEt3)6] and [Pd10(μ-CO)63-CO)2(μ-CNXylyl)2(PEt3)6]." Croatica Chemica Acta 68, br. 4 (1995): 745-767. https://hrcak.srce.hr/136691
Harvard
Mingos, D.M.P., i Hill, C.M. (1995). 'Synthesis and Characterisation of [Pd10(μ-CO)(μ3-CO)4(PEt3)6] and [Pd10(μ-CO)63-CO)2(μ-CNXylyl)2(PEt3)6]', Croatica Chemica Acta, 68(4), str. 745-767. Preuzeto s: https://hrcak.srce.hr/136691 (Datum pristupa: 21.04.2021.)
Vancouver
Mingos DMP, Hill CM. Synthesis and Characterisation of [Pd10(μ-CO)(μ3-CO)4(PEt3)6] and [Pd10(μ-CO)63-CO)2(μ-CNXylyl)2(PEt3)6]. Croatica Chemica Acta [Internet]. 1995 [pristupljeno 21.04.2021.];68(4):745-767. Dostupno na: https://hrcak.srce.hr/136691
IEEE
D.M.P. Mingos i C.M. Hill, "Synthesis and Characterisation of [Pd10(μ-CO)(μ3-CO)4(PEt3)6] and [Pd10(μ-CO)63-CO)2(μ-CNXylyl)2(PEt3)6]", Croatica Chemica Acta, vol.68, br. 4, str. 745-767, 1995. [Online]. Dostupno na: https://hrcak.srce.hr/136691. [Citirano: 21.04.2021.]

Sažetak
The decanuclear palladium cluster compounds [Pdio(u-CO)g(^3-CO)4 (PEtglg] and [Pdio(/(-CO)g(ii3-CO)2(//-CNXyl)2(PEt3)g] (Xyl = CgH^M^- 2,6) have been synthesised and characterised by a combination of spectroscopic data and single crystal X-ray crystallographic analyses. The former has a distorted tetracapped octahedral skeletal geometry and the latter a hexacapped tetrahedral geometry. The latter is unique in cluster chemistry and the structural change induced by the addition of isocyanide represents an interesting example of the effect of the steric requirements of the isocyanide ligand influencing the total electron count and geometry of the cluster. [Pdio(/<-CO)8(/i3-CO)4(PEt3)g] reacts with SO2 to give [Pd5(/(-S02)2(p3-S02)2(PEt3)5].

Hrčak ID: 136691

URI
https://hrcak.srce.hr/136691

Posjeta: 288 *