Croatica Chemica Acta, Vol. 68 No. 4, 1995.
Izvorni znanstveni članak
An Octahedral Rhenium Cluster with (CN) Ligands: the Crystal Structure of KCs3Re6S8(CN)6
Anissa Slougui
; Laboratoire de Chimie du Solide et Inorganique Moléculaire, URA CNRS 1495, Université de Rennes I, Avenue du Général Leclerc, 35042 Rennes Cédex, France
Yuri V. Mironov
; Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Science, 3 Acad. Lavrentiev pr., Novosibirsk 630090, Russia
André Perrin
; Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Science, 3 Acad. Lavrentiev pr., Novosibirsk 630090, Russia
Vladimir E. Fedorov
; Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Science, 3 Acad. Lavrentiev pr., Novosibirsk 630090, Russia
Sažetak
The title compound has been prepared by anionic exchange from ReeTe15. The structure has been solved from the single crystal X- ray diffraction data. The compound is built of standard MgLgL'g units where L are chalcogens in inner position and L' are apical (CN) groups. The K+ ion is octahedrally surrounded by apical ligands belonging to six different units, while the Cs+ ions lie in complex anionic site.
Ključne riječi
Hrčak ID:
136700
URI
Datum izdavanja:
1.11.1995.
Posjeta: 725 *