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On a New Mechanism of S-O Scission in the Solvolysis of Aryl Triflates

Takaaki Sonoda ; Research Institute of Industrial Science, Kyushu University, Kasuga Sakamoto, Fukuoka 816, Japan
Antonio Garcia Martinez ; Departamento Quimica Orgánica, Facultad de Ciencias Quimicas, Univesidad Complutense, E-28040 Madrid, Spain
Michael Hanack ; Institut für Organische Chemie der Universitàt Tübingen, Auf der Morgenstelle 18, D-7400 Tübingen, Germany
L. R. Subramanian ; Institut für Organische Chemie der Universitàt Tübingen, Auf der Morgenstelle 18, D-7400 Tübingen, Germany

Puni tekst: engleski, pdf (16 MB) str. 585-592 preuzimanja: 158* citiraj
APA 6th Edition
Sonoda, T., Garcia Martinez, A., Hanack, M. i Subramanian, L.R. (1992). On a New Mechanism of S-O Scission in the Solvolysis of Aryl Triflates. Croatica Chemica Acta, 65 (3), 585-592. Preuzeto s https://hrcak.srce.hr/137119
MLA 8th Edition
Sonoda, Takaaki, et al. "On a New Mechanism of S-O Scission in the Solvolysis of Aryl Triflates." Croatica Chemica Acta, vol. 65, br. 3, 1992, str. 585-592. https://hrcak.srce.hr/137119. Citirano 20.04.2021.
Chicago 17th Edition
Sonoda, Takaaki, Antonio Garcia Martinez, Michael Hanack i L. R. Subramanian. "On a New Mechanism of S-O Scission in the Solvolysis of Aryl Triflates." Croatica Chemica Acta 65, br. 3 (1992): 585-592. https://hrcak.srce.hr/137119
Harvard
Sonoda, T., et al. (1992). 'On a New Mechanism of S-O Scission in the Solvolysis of Aryl Triflates', Croatica Chemica Acta, 65(3), str. 585-592. Preuzeto s: https://hrcak.srce.hr/137119 (Datum pristupa: 20.04.2021.)
Vancouver
Sonoda T, Garcia Martinez A, Hanack M, Subramanian LR. On a New Mechanism of S-O Scission in the Solvolysis of Aryl Triflates. Croatica Chemica Acta [Internet]. 1992 [pristupljeno 20.04.2021.];65(3):585-592. Dostupno na: https://hrcak.srce.hr/137119
IEEE
T. Sonoda, A. Garcia Martinez, M. Hanack i L.R. Subramanian, "On a New Mechanism of S-O Scission in the Solvolysis of Aryl Triflates", Croatica Chemica Acta, vol.65, br. 3, str. 585-592, 1992. [Online]. Dostupno na: https://hrcak.srce.hr/137119. [Citirano: 20.04.2021.]

Sažetak
The solvolysis of 3,3-di-tert-butyl-4-hvdroxyphenyl triflate (7) in tri- fluoroethanol buffered with the non-nucleophilic base, 2,G-di-tert-butyl-4-methylpyridine proceeds surprisingly fast. This phenomenon is explained by a new type of elimination of triflinate anion from the conjugate base 10 of the triflate 7 to form 2,6-di-tert-butyl-1,4-benzoquinone.

Hrčak ID: 137119

URI
https://hrcak.srce.hr/137119

Posjeta: 295 *