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Synthesis of Aryl-sulphinyl Acetic Acids and Sulphoximides, and CD of their in situ Complexes with [MO2(OAc)4]

J. Drabowicz ; PAN, Centrum Badan Molekularnych i Makromolekularnych Zaklad organicznych zwiazkow siarki PL-90-362, Lodz, (Poland)
M. Mikolajczyk ; PAN, Centrum Badan Molekularnych i Makromolekularnych Zaklad organicznych zwiazkow siarki PL-90-362, Lodz, (Poland)
G. Snatzke ; Ruhruniversitiat Bochum, Lehrstuhl fur Strukturchemie, D-4630 Bochum, (F. R. Germany)


Puni tekst: engleski pdf 1.761 Kb

verzije

str. 423-428

preuzimanja: 161

citiraj


Sažetak

The syntheses of several optically active aryl-sulphinyl acetic acids and sulphoximides are described. They all give two or more Cotton effects in the presence of the metal cluster [MO2(OAc)4]in DMSO solution above 300 nm, from which their absolute configuration can be determined unequivocally.

Ključne riječi

Hrčak ID:

175508

URI

https://hrcak.srce.hr/175508

Datum izdavanja:

10.8.1989.

Posjeta: 457 *