Croatica Chemica Acta, Vol. 47 No. 2, 1975.
Kratko priopćenje
Dependence of Rates of Substitution Reactions of Pentacyanoaquoiron(II) Ion on Ionic Strength
A. Žmikić
; Department of Chemistry, Faculty of Pharmacy and Biochemistry, University of Zagreb
M. Pribanić
; Department of Chemistry, Faculty of Pharmacy and Biochemistry, University of Zagreb
D. Pavlović
; Department of Chemistry, Faculty of Pharmacy and Biochemistry, University of Zagreb
S. Ašperger
; Department of Chemistry, Faculty of Pharmacy and Biochemistry, University of Zagreb
Sažetak
The second-order rate constants (k) of substitution of water
in pentacyanoaquo:iron(II) ion by nitrite, thiocyanate, sulphite or
nitrobenzene were determined at various ionic strengths {I) in
aqueous solution at 25 oc. The following slopes of the plot of log
k versus J'h were obtained : 2.9 (No2-·), 2.5 (SCN-), 4.4 (S0a2-), and
zero (nitrosobenzene).
Ključne riječi
Hrčak ID:
196667
URI
Datum izdavanja:
15.10.1975.
Posjeta: 708 *