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https://doi.org/10.5562/cca3247

Great Efficiency of Nucleosides as Organizing Tools

Sonja Merkaš ; CNRS, 205 route de Narbonne, 31077 Toulouse, France; Université de Toulouse, UPS, INPT, 31077 Toulouse, France
Souhaila Bouatra ; CNRS, 205 route de Narbonne, 31077 Toulouse, France; Université de Toulouse, UPS, INPT, 31077 Toulouse, France
Régis Rein ; CNRS, 205 route de Narbonne, 31077 Toulouse, France; Université de Toulouse, UPS, INPT, 31077 Toulouse, France
Ivo Piantanida ; Laboratory of Supramolecular and Nucleoside Chemistry, Ruđer Bošković Institute, Bijenička c. 54, HR-10000 Zagreb, Croatia
Mladen Žinić ; Laboratory of Supramolecular and Nucleoside Chemistry, Ruđer Bošković Institute, Bijenička c. 54, HR-10000 Zagreb, Croatia
Nathalie Solladié ; CNRS, 205 route de Narbonne, 31077 Toulouse, France; Université de Toulouse, UPS, INPT, 31077 Toulouse, France

Puni tekst: engleski, pdf (6 MB) str. 595-602 preuzimanja: 177* citiraj
APA 6th Edition
Merkaš, S., Bouatra, S., Rein, R., Piantanida, I., Žinić, M. i Solladié, N. (2017). Great Efficiency of Nucleosides as Organizing Tools. Croatica Chemica Acta, 90 (4), 595-602. https://doi.org/10.5562/cca3247
MLA 8th Edition
Merkaš, Sonja, et al. "Great Efficiency of Nucleosides as Organizing Tools." Croatica Chemica Acta, vol. 90, br. 4, 2017, str. 595-602. https://doi.org/10.5562/cca3247. Citirano 18.10.2019.
Chicago 17th Edition
Merkaš, Sonja, Souhaila Bouatra, Régis Rein, Ivo Piantanida, Mladen Žinić i Nathalie Solladié. "Great Efficiency of Nucleosides as Organizing Tools." Croatica Chemica Acta 90, br. 4 (2017): 595-602. https://doi.org/10.5562/cca3247
Harvard
Merkaš, S., et al. (2017). 'Great Efficiency of Nucleosides as Organizing Tools', Croatica Chemica Acta, 90(4), str. 595-602. https://doi.org/10.5562/cca3247
Vancouver
Merkaš S, Bouatra S, Rein R, Piantanida I, Žinić M, Solladié N. Great Efficiency of Nucleosides as Organizing Tools. Croatica Chemica Acta [Internet]. 2017 [pristupljeno 18.10.2019.];90(4):595-602. https://doi.org/10.5562/cca3247
IEEE
S. Merkaš, S. Bouatra, R. Rein, I. Piantanida, M. Žinić i N. Solladié, "Great Efficiency of Nucleosides as Organizing Tools", Croatica Chemica Acta, vol.90, br. 4, str. 595-602, 2017. [Online]. https://doi.org/10.5562/cca3247

Sažetak
Bis-porphyrins with flexible linkers such as uridine or 2’-deoxyuridin pre-organize in a face-to-face conformation and form stable sandwich complexes with bidentate base such as DABCO. The gain in stability can be even greater when a dinucleotide linker is used. Such pre-organization increases the association constant by one to two orders of magnitude when compared to the one of DABCO with a reference porphyrin. Comparison with rigid tweezers shows a better efficiency of nucleosidic dimers. The choice of rigid spacers is not the only way to pre-organize bis-porphyrins, and well-chosen nucleosidic linkers offer an interesting option for the synthesis of such devices.

Creative Commons License This work is licensed under a Creative Commons Attribution 4.0 International License.

Ključne riječi
porphyrins; tweezers; nucleosides; molecular recognition

Hrčak ID: 198181

URI
https://hrcak.srce.hr/198181

Posjeta: 246 *