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https://doi.org/10.5562/cca3270

A Case Study of Supramolecular Organization: One Ferrocene Substituted Iminodiacetamide and its Chloroform Solvate

Natalija P. Juraj   ORCID icon orcid.org/0000-0002-0357-5817 ; Ruđer Bošković Institute, Bijenička c. 54, HR-10000 Zagreb, Croatia
Jeremy Le Pennec ; Ruđer Bošković Institute, Bijenička c. 54, HR-10000 Zagreb, Croatia
Berislav Perić   ORCID icon orcid.org/0000-0002-2397-2836 ; Ruđer Bošković Institute, Bijenička c. 54, HR-10000 Zagreb, Croatia
Srećko I. Kirin   ORCID icon orcid.org/0000-0002-0500-2422 ; Ruđer Bošković Institute, Bijenička c. 54, HR-10000 Zagreb, Croatia

Puni tekst: engleski, pdf (6 MB) str. 613-623 preuzimanja: 218* citiraj
APA 6th Edition
Juraj, N.P., Le Pennec, J., Perić, B. i Kirin, S.I. (2017). A Case Study of Supramolecular Organization: One Ferrocene Substituted Iminodiacetamide and its Chloroform Solvate. Croatica Chemica Acta, 90 (4), 613-623. https://doi.org/10.5562/cca3270
MLA 8th Edition
Juraj, Natalija P., et al. "A Case Study of Supramolecular Organization: One Ferrocene Substituted Iminodiacetamide and its Chloroform Solvate." Croatica Chemica Acta, vol. 90, br. 4, 2017, str. 613-623. https://doi.org/10.5562/cca3270. Citirano 20.10.2019.
Chicago 17th Edition
Juraj, Natalija P., Jeremy Le Pennec, Berislav Perić i Srećko I. Kirin. "A Case Study of Supramolecular Organization: One Ferrocene Substituted Iminodiacetamide and its Chloroform Solvate." Croatica Chemica Acta 90, br. 4 (2017): 613-623. https://doi.org/10.5562/cca3270
Harvard
Juraj, N.P., et al. (2017). 'A Case Study of Supramolecular Organization: One Ferrocene Substituted Iminodiacetamide and its Chloroform Solvate', Croatica Chemica Acta, 90(4), str. 613-623. https://doi.org/10.5562/cca3270
Vancouver
Juraj NP, Le Pennec J, Perić B, Kirin SI. A Case Study of Supramolecular Organization: One Ferrocene Substituted Iminodiacetamide and its Chloroform Solvate. Croatica Chemica Acta [Internet]. 2017 [pristupljeno 20.10.2019.];90(4):613-623. https://doi.org/10.5562/cca3270
IEEE
N.P. Juraj, J. Le Pennec, B. Perić i S.I. Kirin, "A Case Study of Supramolecular Organization: One Ferrocene Substituted Iminodiacetamide and its Chloroform Solvate", Croatica Chemica Acta, vol.90, br. 4, str. 613-623, 2017. [Online]. https://doi.org/10.5562/cca3270

Sažetak
This paper describes the synthesis of an amide based conjugate of ferrocene (Fc), ethylenediamine (eda) and iminodiacetamide (imda), Fc-eda-imda (2). The compound (2) is characterized by various spectroscopic, crystallographic and thermoanalytical techniques in solid state and in solution. By crystallization of the title compound 2 from methanol or chloroform, two different crystalline forms 2a and 2b were obtained, respectively. In their X-ray single crystal structures, 2a and 2b reveal similar 2D hydrogen bonding networks, but differ by supramolecular organization, namely aromatic π – π stacking interactions in the third spatial dimension.

Creative Commons License This work is licensed under a Creative Commons Attribution 4.0 International License.

Ključne riječi
amides; ferrocene; hydrogen bonding; iminodiacetamide; supramolecular chemistry

Hrčak ID: 198485

URI
https://hrcak.srce.hr/198485

Posjeta: 298 *