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https://doi.org/10.5562/cca3485

Simulation of Alternative Differential Multi-pulse Voltammetry. Evaluation of the Electrochemical Reversibility by the Voltammogram Symmetry

Dijana Jadreško ; Division for Marine and Environmental Research, Ruđer Bošković Institute, P.O. Box 180, HR-10002 Zagreb, Croatia

Puni tekst: engleski, pdf (5 MB) str. 95-102 preuzimanja: 137* citiraj
APA 6th Edition
Jadreško, D. (2019). Simulation of Alternative Differential Multi-pulse Voltammetry. Evaluation of the Electrochemical Reversibility by the Voltammogram Symmetry. Croatica Chemica Acta, 92 (1), 95-102. https://doi.org/10.5562/cca3485
MLA 8th Edition
Jadreško, Dijana. "Simulation of Alternative Differential Multi-pulse Voltammetry. Evaluation of the Electrochemical Reversibility by the Voltammogram Symmetry." Croatica Chemica Acta, vol. 92, br. 1, 2019, str. 95-102. https://doi.org/10.5562/cca3485. Citirano 08.12.2019.
Chicago 17th Edition
Jadreško, Dijana. "Simulation of Alternative Differential Multi-pulse Voltammetry. Evaluation of the Electrochemical Reversibility by the Voltammogram Symmetry." Croatica Chemica Acta 92, br. 1 (2019): 95-102. https://doi.org/10.5562/cca3485
Harvard
Jadreško, D. (2019). 'Simulation of Alternative Differential Multi-pulse Voltammetry. Evaluation of the Electrochemical Reversibility by the Voltammogram Symmetry', Croatica Chemica Acta, 92(1), str. 95-102. https://doi.org/10.5562/cca3485
Vancouver
Jadreško D. Simulation of Alternative Differential Multi-pulse Voltammetry. Evaluation of the Electrochemical Reversibility by the Voltammogram Symmetry. Croatica Chemica Acta [Internet]. 2019 [pristupljeno 08.12.2019.];92(1):95-102. https://doi.org/10.5562/cca3485
IEEE
D. Jadreško, "Simulation of Alternative Differential Multi-pulse Voltammetry. Evaluation of the Electrochemical Reversibility by the Voltammogram Symmetry", Croatica Chemica Acta, vol.92, br. 1, str. 95-102, 2019. [Online]. https://doi.org/10.5562/cca3485

Sažetak
A theoretical analysis of reversible and kinetically controlled electrode reactions in conditions of alternative differential multi-pulse voltammetry (ADMPV) is presented. The degree of reversibility, as well as symmetry of the electron transfer reaction, can be estimated by visual inspection of the ADMP voltammogram. The values of electron transfer coefficient and the standard rate constant of a simple electrode reaction Ox + ne− ⇄ Red, can be determined from the slope of linear dependence of the peak currents ratio on the logarithm of pulse duration. The criteria for recognition of reversible and kinetically controlled electrode reactions by alternative differential multi-pulse voltammetry are given.

Creative Commons License This work is licensed under a Creative Commons Attribution 4.0 International License.

Ključne riječi
alternative differential multi-pulse voltammetry; excitation signal; kinetics; symmetry; theory

Hrčak ID: 221404

URI
https://hrcak.srce.hr/221404

Posjeta: 238 *