Croatica Chemica Acta, Vol. 29 No. 3-4, 1957.
Izvorni znanstveni članak
The Use of Silver Phenyl Benzyl Phosphate for the Synthesis of Monophenyl Esters of Phosphatidic Acids
P. E. Verkade
; Laboratory of Organic Chemistry, Technical University, Delft, Netherlands
L. J. Stegerhoek
; Laboratory of Organic Chemistry, Technical University, Delft, Netherlands
S. Mostert Pzn
; Laboratory of Organic Chemistry, Technical University, Delft, Netherlands
Sažetak
Hessel, Morton, Todd, and Verkade have shown that dibenzyl esters of a-glycerophosphatidic acids I (D = acyl group), when shaken at room temperature in an ethanolic medium with hydrogen under slightly more than atmospheric pressure in the presence of a palladium/ active carbon catalyst according to Verkade, Cohen, and Vroege are smoothly hydrogenolyzed; 2 moles of hydrogen per mole of ester are rapidly absorbed, resulting in the formation of the corresponding phosphatidic acids and toluene.
Ključne riječi
Hrčak ID:
246322
URI
Datum izdavanja:
30.12.1957.
Posjeta: 536 *