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Synthesis of Optically Active 2-Aminooctadecanes

M. Munk-Weinert ; Department of Chemistry, Medical Faculty, University of Zagreb, Croatia, Yu.goslavia
M. Proštenik ; Department of Chemistry, Medical Faculty, University of Zagreb, Croatia, Yu.goslavia

Sažetak

2-Octadecanone has been converted to DL-2-benzylaminooctadecane by reductive amination with benzylamine. The resolution of the racemic base has been effected through its salts with benzoyl-L-alanine and benzioyl-D-alanine. Both enantiomeric bases were debenzylated hydrogenolytically to give (+) and (-)-2-aminooctadecane. A series of derivatives of the racemic and of the optically active base has been prepared.

Ključne riječi

Hrčak ID:

249423

URI

https://hrcak.srce.hr/249423

Datum izdavanja:

31.7.1954.

Posjeta: 663 *