Skoči na glavni sadržaj

Journal of Electrochemical Science and Engineering, Vol. 13 No. 6, 2023.

Izvorni znanstveni članak

https://doi.org/10.5599/jese.1899

Influence of polarization curve slope on the accuracy of local copper electrodeposition from sulphate electrolyte

Georgii Vasyliev orcid id orcid.org/0000-0003-4056-5551 ; National Technical University of Ukraine “Igor Sikorsky Kyiv Polytechnic Institute”, 37, Prospect Peremohy, Kyiv-56, 03056, Ukraine *
Viktoria Vorobyova orcid id orcid.org/0000-0001-7479-9140 ; National Technical University of Ukraine “Igor Sikorsky Kyiv Polytechnic Institute”, 37, Prospect Peremohy, Kyiv-56, 03056, Ukraine
Dmytro Uschapovskiy orcid id orcid.org/0000-0002-2809-2774 ; National Technical University of Ukraine “Igor Sikorsky Kyiv Polytechnic Institute”, 37, Prospect Peremohy, Kyiv-56, 03056, Ukraine
Mykhailo Kotyk ; National Technical University of Ukraine “Igor Sikorsky Kyiv Polytechnic Institute”, 37, Prospect Peremohy, Kyiv-56, 03056, Ukraine
Olga Linyucheva ; National Technical University of Ukraine “Igor Sikorsky Kyiv Polytechnic Institute”, 37, Prospect Peremohy, Kyiv-56, 03056, Ukraine

* Dopisni autor.

Puni tekst: engleski pdf 1.355 Kb

str. 971-980

preuzimanja: 139

citiraj

Sažetak

Local electrochemical deposition is an emerging technique, used in the field of additive manufacturing. The advantage of electrochemical additive manufacturing lies in the utilization of room temperature electrolyte and permits to manufacture microscale objects with high precision. The increase in deposition current increases the deposition area, so measures are to be taken to focus the electric field. This work describes the influence of polarization curve slope on the accuracy of local deposition, both experimentally and by computer modelling. The copper was deposited using rotating anode on the surface of stainless steel from sulphate electrolyte. The influence of electrolyte composition on the accuracy of deposition was investigated. The profile of deposited parts was analyzed by profilometry and microscopy. The increased amount of sulfuric acid and presence of the additive in the electrolyte was shown to increase the accuracy of deposition by changing the slope of cathodic polarization curve from 320 to 1100 mA V–1cm–2).

Ključne riječi

Additive manufacturing; 3D printing; copper electroplating; throwing power, profilometry

Hrčak ID:

311016

URI

https://hrcak.srce.hr/311016

Datum izdavanja:

7.12.2023.

Posjeta: 465 *