Izvorni znanstveni članak

Molecular disorder at phase transitions of n-alkanes

Jasna Baturić-Rubčić ; Faculty of Science, University of Zagreb, 41000 Zagreb, Yugoslavia
Anton Rubčić ; Faculty of Science, University of Zagreb, 41000 Zagreb, Yugoslavia

Sažetak

The homologous series of n-alkanes, with solid-to-solid phase transitions following fusion, are considered. By means of available experimental data, the total fusion entropy is resolved into its volume and disorder contributions. Their dependences on the number of carbon atoms per molecule are compared with that recently evaluated for those even n-alkanes, which reach their final crystal form immediately after solidification. Thus, an insight into changes of molecular disorder, both at fusion and solid transition, is presented.

Ključne riječi

Hrčak ID:

328935

URI

https://hrcak.srce.hr/328935

Datum izdavanja:

5.12.1983.

Podaci na drugim jezicima: hrvatski

Posjeta: 160 *