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Izvorni znanstveni članak
On a Possible Role of Dicarboxylate Ions in the Formation of Open-framework Metallophosphates
Nevenka Rajić
Nataša Zabukovec Logar
Gregor Mali
Djordje Stojaković
Venčeslav Kaučoč
| Puni tekst: engleski, pdf (454 KB) | str. 187-193 | citiraj | |
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APA 6th Edition Rajić, N., Zabukovec Logar, N., Mali, G., Stojaković, D. i Kaučoč, V. (2006). On a Possible Role of Dicarboxylate Ions in the Formation of Open-framework Metallophosphates. Croatica Chemica Acta, 79 (2), 187-193. Preuzeto s https://hrcak.srce.hr/4123 MLA 8th Edition Rajić, Nevenka, et al. "On a Possible Role of Dicarboxylate Ions in the Formation of Open-framework Metallophosphates." Croatica Chemica Acta, vol. 79, br. 2, 2006, str. 187-193. https://hrcak.srce.hr/4123. Citirano 27.05.2020. Chicago 17th Edition Rajić, Nevenka, Nataša Zabukovec Logar, Gregor Mali, Djordje Stojaković i Venčeslav Kaučoč. "On a Possible Role of Dicarboxylate Ions in the Formation of Open-framework Metallophosphates." Croatica Chemica Acta 79, br. 2 (2006): 187-193. https://hrcak.srce.hr/4123 Harvard Rajić, N., et al. (2006). 'On a Possible Role of Dicarboxylate Ions in the Formation of Open-framework Metallophosphates', Croatica Chemica Acta, 79(2), str. 187-193. Preuzeto s: https://hrcak.srce.hr/4123 (Datum pristupa: 27.05.2020.) Vancouver Rajić N, Zabukovec Logar N, Mali G, Stojaković D, Kaučoč V. On a Possible Role of Dicarboxylate Ions in the Formation of Open-framework Metallophosphates. Croatica Chemica Acta [Internet]. 2006 [pristupljeno 27.05.2020.];79(2):187-193. Dostupno na: https://hrcak.srce.hr/4123 IEEE N. Rajić, N. Zabukovec Logar, G. Mali, D. Stojaković i V. Kaučoč, "On a Possible Role of Dicarboxylate Ions in the Formation of Open-framework Metallophosphates", Croatica Chemica Acta, vol.79, br. 2, str. 187-193, 2006. [Online]. Dostupno na: https://hrcak.srce.hr/4123. [Citirano: 27.05.2020.] |
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Sažetak
Three dicarboxylic acids (oxalic, malonic and terephthalic) were investigated as possible pillars in the formation of metallophosphates with extended structures in the presence of 1,2-diaminopropane (DAP) as a structure-directing agent. Only the oxalate ion was proven to be a suitable building block in the formation of hybrid networks. The terephthalate ion seems to possess the ability to be structurally involved in lattice formation, although not in networks of the hybrid type. The malonate ion in this system showed no propensity towards lattice formation, i.e., malonic acid merely exits as an intercalated species inside the 2–D zincophosphate structure. Different pillar-functioning ability has been attributed to structural differences of the
three dicarboxylate ions.
Ključne riječi
open-framework: inorganic-organic hybrid; template; dicarboxylate; porous; hydrothermal synthesis
Hrčak ID: 4123
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