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Kemija u industriji : Časopis kemičara i kemijskih inženjera Hrvatske, Vol. 67 No. 13 (special issue), 2018.

Izvorni znanstveni članak

https://doi.org/10.15255/KUI.2018.021

Mechanochemical Synthesis of Calcium Oxalate

Silvija Šafranko ; Odjel za kemiju, Sveučilište u Osijeku, Ulica cara Hadrijana 8A, 31 000 Osijek, Hrvatska
Dominik Goman ; Odjel za kemiju, Sveučilište u Osijeku, Ulica cara Hadrijana 8A, 31 000 Osijek, Hrvatska
Filip Bolić ; Odjel za kemiju, Sveučilište u Osijeku, Ulica cara Hadrijana 8A, 31 000 Osijek, Hrvatska
Marina Sekulić ; Odjel za kemiju, Sveučilište u Osijeku, Ulica cara Hadrijana 8A, 31 000 Osijek, Hrvatska
Anamarija Stanković ; Odjel za kemiju, Sveučilište u Osijeku, Ulica cara Hadrijana 8A, 31 000 Osijek, Hrvatska
Nives Matijaković orcid id orcid.org/0000-0002-3751-1790 ; Institut Ruđer Bošković, Laboratorij za procese taloženja, Bijenička cesta 54, 10 000 Zagreb, Hrvatska
Ina Erceg ; Institut Ruđer Bošković, Laboratorij za biokoloide i površinsku kemiju, Bijenička cesta 54, 10 000 Zagreb
Berislav Marković ; Odjel za kemiju, Sveučilište u Osijeku, Ulica cara Hadrijana 8A, 31 000 Osijek, Hrvatska

Puni tekst: hrvatski pdf 2.202 Kb

str. P73-P83

preuzimanja: 735

citiraj

Sažetak

In this work, mechanochemical synthesis of calcium oxalate was done in a planetary ball mill, with and without addition of water as a solvent. Previous research was primarily focused on calcium oxalate synthesis in solution. Here we report a different approach which may contribute to new findings in calcium oxalate crystal synthesis caused by an influence of mechanical energy.
The aim of this study was synthesis, identification, and characterization of particular oxalate hydrate phase synthesized with calcium salts (chloride, nitrate and sulphate). The effects of grinding speed and reaction duration regarding the time of synthesis were investigated. Structural and thermal sample properties were studied by FTIR spectroscopy and thermogravimetric analysis (TGA). Morphologic characteristics of calcium oxalate and size distribution were measured by optical microscopy and dynamic light scattering (DLS).


This work is licensed under a Creative Commons Attribution 4.0 International License.

Ključne riječi

mechanochemistry; calcium oxalate monohydrate; kidney stones

Hrčak ID:

207070

URI

https://hrcak.srce.hr/207070

Datum izdavanja:

14.12.2018.

Podaci na drugim jezicima: hrvatski

Posjeta: 1.777 *