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Ligand Field Splitting of d-Orbitals in Eight Coordinated Complexes of Square Antiprism Structure

M. Randić ; Department of Physical Chemistry Institute Ruder Boskovic, Zagreb, Croatia,Yugoslavia


Puni tekst: engleski pdf 2.639 Kb

str. 189-192

preuzimanja: 346

citiraj


Sažetak

The spliUing of d-orbitals in the ligand field of a square antiprism
structure is given. Fivefold degenerate level splits into
A1 + E2+ E 3. The energy order of d orbitals is obtained from known
order of d orbitals in a cube considering the effect of distortion
of a cube into an antiprism on each of d orbitals. It foll ows that
dz2 orbital is substantially more stable than others.

Ključne riječi

Hrčak ID:

208591

URI

https://hrcak.srce.hr/208591

Posjeta: 469 *