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Gas Phase Ligation of U+. Comparison of Pyrene, Phenanthridine and Phenanthrene as Ligands

Saša Kazazić
Snježana P. Kazazić
Leo Klasinc
Marko Rožman
Dunja Srzić


Puni tekst: engleski pdf 139 Kb

str. 125-128

preuzimanja: 470

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Sažetak

Ligation of U+ with phenanthrene in an FT ICR MS instrument is compared with previous results on U+ with pyrene and phenanthridine. All investigated processes compete with U+ oxidation by water and oxygen traces in the instrument. The comparison indicates that oxidation preferentially involves dehydrogenated ligation products.

Ključne riječi

ligation reaction, gas phase kinetics, uranium monocation, pyrene, phenanthridine, phenanthrene, FT ICR MS

Hrčak ID:

2622

URI

https://hrcak.srce.hr/2622

Podaci na drugim jezicima: hrvatski

Posjeta: 1.078 *