Croatica Chemica Acta, Vol. 79 No. 1, 2006.
Izvorni znanstveni članak
Gas Phase Ligation of U+. Comparison of Pyrene, Phenanthridine and Phenanthrene as Ligands
Saša Kazazić
Snježana P. Kazazić
Leo Klasinc
Marko Rožman
Dunja Srzić
Sažetak
Ligation of U+ with phenanthrene in an FT ICR MS instrument is compared with previous results on U+ with pyrene and phenanthridine. All investigated processes compete with U+ oxidation by water and oxygen traces in the instrument. The comparison indicates that oxidation preferentially involves dehydrogenated ligation products.
Ključne riječi
ligation reaction, gas phase kinetics, uranium monocation, pyrene, phenanthridine, phenanthrene, FT ICR MS
Hrčak ID:
2622
URI
Posjeta: 1.078 *