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Gas Phase Ligation of U+. Comparison of Pyrene, Phenanthridine and Phenanthrene as Ligands

Saša Kazazić
Snježana P. Kazazić
Leo Klasinc
Marko Rožman
Dunja Srzić


Puni tekst: engleski pdf 139 Kb

str. 125-128

preuzimanja: 537

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Sažetak

Ligation of U+ with phenanthrene in an FT ICR MS instrument is compared with previous results on U+ with pyrene and phenanthridine. All investigated processes compete with U+ oxidation by water and oxygen traces in the instrument. The comparison indicates that oxidation preferentially involves dehydrogenated ligation products.

Ključne riječi

ligation reaction; gas phase kinetics; uranium monocation; pyrene; phenanthridine; phenanthrene; FT ICR MS

Hrčak ID:

2622

URI

https://hrcak.srce.hr/2622

Datum izdavanja:

22.4.2006.

Podaci na drugim jezicima: hrvatski

Posjeta: 1.577 *