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https://doi.org/10.15255/KUI.2025.015

Recent Advances in the Catalytic Epoxidation of Oleic Acid for Bio-polyol Synthesis: Challenges and Opportunities

Muhammad Akhiruddin Zainal Abidin ; Faculty of Chemical Engineering, Universiti Teknologi MARA Cawangan Johor, Kampus Pasir Gudang, 81 750 Masai, Johor, Malezija
Ismail Md Rasib ; Faculty of Chemical Engineering, Universiti Teknologi MARA Cawangan Johor, Kampus Pasir Gudang, 81 750 Masai, Johor, Malezija
Mohd Jumain Jalil ; Faculty of Chemical Engineering, Universiti Teknologi MARA Cawangan Johor, Kampus Pasir Gudang, 81 750 Masai, Johor, Malezija
Mar'atul Fauziyah ; Department of Chemical Engineering, Faculty of Engineering, Universitas Brawijaya, Malang, Indonezija
Siti Juwairiyah A. Rahman ; Faculty of Chemical Engineering, Universiti Teknologi MARA Cawangan Johor, Kampus Pasir Gudang, 81 750 Masai, Johor, Malezija
Mohd Azril Riduan ; Comgreat Solution Sdn. Bhd, Chandan Desa, 31 300 Ipoh, Perak, Malezija
Intan Suhada Azmi orcid id orcid.org/0000-0002-1544-1939 ; Faculty of Chemical Engineering, Universiti Teknologi MARA Cawangan Johor, Kampus Pasir Gudang, 81 750 Masai, Johor, Malezija *

* Dopisni autor.


Puni tekst: engleski pdf 263 Kb

str. 83-90

preuzimanja: 90

citiraj


Sažetak

The catalytic epoxidation of oleic acid is a key process in bio-polyol synthesis, offering a renewable alternative to petroleum-based materials. This review explores recent advances in catalyst development, process optimisation, and kinetic modelling, with an emphasis on the transition from conventional homogeneous catalysts to more sustainable heterogeneous alternatives, such as zeolites and metal oxides. Key factors influencing reaction efficiency, including catalyst stability, oxirane retention, and by-product control, are critically analysed. The discussion also highlights industrial applications and potential improvements to enhance process scalability and economic feasibility. This review provides insights into overcoming current challenges and advancing sustainable bio-polyol production.

Ključne riječi

epoxidation; oxirane ring; catalyst; kinetic models; polyol

Hrčak ID:

342975

URI

https://hrcak.srce.hr/342975

Datum izdavanja:

13.1.2026.

Podaci na drugim jezicima: hrvatski

Posjeta: 217 *