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Original scientific paper

Gas Phase Ligation of U+. Comparison of Pyrene, Phenanthridine and Phenanthrene as Ligands

Saša Kazazić
Snježana P. Kazazić
Leo Klasinc
Marko Rožman
Dunja Srzić

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page 125-128

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Ligation of U+ with phenanthrene in an FT ICR MS instrument is compared with previous results on U+ with pyrene and phenanthridine. All investigated processes compete with U+ oxidation by water and oxygen traces in the instrument. The comparison indicates that oxidation preferentially involves dehydrogenated ligation products.


ligation reaction; gas phase kinetics; uranium monocation; pyrene; phenanthridine; phenanthrene; FT ICR MS

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Article data in other languages: croatian

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