Original scientific paper

https://doi.org/10.5562/cca3907

Transition Metal-Mediated Hydrolysis of the Imine Bond in 2-Azomethine Benzothiazoles

Valentina Rep Kaulić ; Department of Organic Chemistry, Faculty of Chemical Engineering and Technology, University of Zagreb, Zagreb, Croatia
Natalija Pantalon Juraj orcid.org/0000-0002-0357-5817 ; Laboratory for Solid-State and Complex Compounds Chemistry, Division of Materials Chemistry, Ruđer Bošković Institute, Zagreb, Croatia
Berislav Perić orcid.org/0000-0002-2397-2836 ; Laboratory for Solid-State and Complex Compounds Chemistry, Division of Materials Chemistry, Ruđer Bošković Institute, Zagreb, Croatia
Zoran Štefanić ; Laboratory for Chemical and Biological Crystallography, Division of Physical Chemistry, Ruđer Bošković Institute, Zagreb, Croatia
Srećko I. Kirin orcid.org/0000-0002-0500-2422 ; Laboratory for Solid-State and Complex Compounds Chemistry, Division of Materials Chemistry, Ruđer Bošković Institute, Zagreb, Croatia
Silvana Raić-Malić orcid.org/0000-0001-5021-8970 ; Department of Organic Chemistry, Faculty of Chemical Engineering and Technology, University of Zagreb, Zagreb, Croatia

Supplements: cca3907-supplement.pdf

Abstract

An ultrasound-assisted synthesis has been used for the preparation of novel benzothiazole Schiff bases (1–3) as ligands for Zn(II) and Cu(II) metal complexes. In this class of Schiff base ligands, the isolated complexes 1a and 2a appear to be the only ones that have structures which include both the Schiff base ligand and the hydrolysis product 2-aminobenzothiazole in the same complex molecule. The aldehydes formed by Schiff base hydrolysis formed a rare example of a trans-isomer in pentacoordinated 2,4-disubstituted benzaldehyde complexes.

Keywords

ultrasound-assisted synthesis; Schiff base; hydrolytic cleavage; metal complexes

Hrčak ID:

305502

URI

https://hrcak.srce.hr/305502

Publication date:

5.7.2023.

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