Original scientific paper

An Octahedral Rhenium Cluster with (CN) Ligands: the Crystal Structure of KCs₃Re₆S₈(CN)₆

Anissa Slougui ; Laboratoire de Chimie du Solide et Inorganique Moléculaire, URA CNRS 1495, Université de Rennes I, Avenue du Général Leclerc, 35042 Rennes Cédex, France
Yuri V. Mironov ; Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Science, 3 Acad. Lavrentiev pr., Novosibirsk 630090, Russia
André Perrin ; Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Science, 3 Acad. Lavrentiev pr., Novosibirsk 630090, Russia
Vladimir E. Fedorov ; Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Science, 3 Acad. Lavrentiev pr., Novosibirsk 630090, Russia

Abstract

The title compound has been prepared by anionic exchange from ReeTe15. The structure has been solved from the single crystal X- ray diffraction data. The compound is built of standard MgLgL'g units where L are chalcogens in inner position and L' are apical (CN) groups. The K+ ion is octahedrally surrounded by apical ligands belonging to six different units, while the Cs+ ions lie in complex anionic site.

Keywords

Hrčak ID:

136700

URI

https://hrcak.srce.hr/136700

Publication date:

1.11.1995.

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