Croatica Chemica Acta, Vol. 57 No. 6, 1984.
Original scientific paper
Non Adiabatic Effects and Radiationless Transitions
Carlo Petrongolo
; Istituto di Chimica Fisica, Via Risorgimento 35, 56100 Pisa, Italy
Abstract
Ab-initio methods for computing stationary molecular states
and radiationless transition probabilities between nonstationary
states are discussed. The expansion methods, the molecular Hamiltonians,
the adiabatic and dia-batic representations, and the symmetry
properties are briefly discussed. As an example, nonadiabatic
effects in the V-N spectrum of C2H4 and corresponding V-R, ·
radiationless transitions in C2H4 are investigated.
Keywords
Hrčak ID:
194039
URI
Publication date:
21.5.1985.
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