Croatica Chemica Acta, Vol. 49 No. 4, 1977.
Original scientific paper
Application of Many-Body Rayleigh-Schrodinger Perturbation Theory to Excitations Accompanying Photoionization in Molecules
I. Hubač
; Department of Mathematics, Slovak Technical University, 88037 Bratislava, . Czechoslovakia
V. Kvasnička
; Department of Mathematics, Slovak Technical University, 88037 Bratislava, . Czechoslovakia
Abstract
Excitations accompanying photoionizations in molecules (shake-
up processes) are studied on the basis of degenerate many-body
Rayleigh-Schr6dinger perturbation theory (MB - RSPT).
These excitations give rise to satellite lines accompanyin ionization
lines. Decomposition of correlation effects in these processes
into those corresponding to single-particle excitation and single-
particle ionization is discussed.
Keywords
Hrčak ID:
196120
URI
Publication date:
26.4.1978.
Visits: 691 *