Croatica Chemica Acta, Vol. 32 No. 4, 1960.
Original scientific paper
Ligand Field Splitting of d-Orbitals in Eight Coordinated Complexes of Square Antiprism Structure
M. Randić
; Department of Physical Chemistry Institute Ruder Boskovic, Zagreb, Croatia,Yugoslavia
Abstract
The spliUing of d-orbitals in the ligand field of a square antiprism
structure is given. Fivefold degenerate level splits into
A1 + E2+ E 3. The energy order of d orbitals is obtained from known
order of d orbitals in a cube considering the effect of distortion
of a cube into an antiprism on each of d orbitals. It foll ows that
dz2 orbital is substantially more stable than others.
Keywords
Hrčak ID:
208591
URI
Publication date:
18.5.1961.
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