Croatica Chemica Acta, Vol. 45 No. 3, 1973.
Izvorni znanstveni članak
On Some Properties of Silver Iodide
R. Despotović
; »Ruder Boskovic« Institute, Zagreb, Croatia, Yugoslavia
Z. Grabarić
; »Ruder Boskovic« Institute, Zagreb, Croatia, Yugoslavia
S. Popović
; »Ruder Boskovic« Institute, Zagreb, Croatia, Yugoslavia
Sažetak
In order to obtain the relation between several factors affecting
the colloido-chemical properties of silver iodide in the heterogeneous
exchange processes, the following measurements were carried
out: determination of the adsorption capacity of silver iodide (radiometry)
tempered from 20 up to 400 °c, dry aged for 20 days to 5
years, pressed at 500 and 1500 kg cm-2 (on dried isoelectric precipitate);
determination of the relation between particle size (electron
microscopy) and crystallite size (X-ray diffraction analysis), and
of the adsorption capacity of AgI (formed by dilution of KI + AgI
complex solution) in the presence of sodium laurylsulphate (SLS);
determination of the surface area (BET) of the tempered isoelectric
dried silver iodide; determination of particle size and determination
of the volume fraction of cubic and hexagonal modifications
of AgI in the tempered samples. In conclusion, the effect of the inner
surface as a possible relevant factor for the elucidation of the
influence of surface active substances on acceleration of the
exchange rate is pointed out. Interactions with sodium laurylsulphate
are also discussed.
Ključne riječi
Hrčak ID:
197013
URI
Datum izdavanja:
12.11.1973.
Posjeta: 567 *