Catalytic Epoxidation of Rice Bran Oil <i>via</i> an <i>In Situ</i> Generated Hybrid Peracids Mechanism

Noorfazlida, Mohamed; Yeop, Mohamad Zarqani; Azmi, Intan Suhada; Rahman, Siti Mariam A.; Morsidi, Nur Izzah Anati; Kamal, Nursyazliana; Nurherdiana, Silvana Dwi; Jalil, Mohd Jumain

doi:10.15255/KUI.2024.045

Kemija u industriji : Časopis kemičara i kemijskih inženjera Hrvatske, Vol. 74 No. 5-6, 2025.

Izvorni znanstveni članak

https://doi.org/10.15255/KUI.2024.045

Catalytic Epoxidation of Rice Bran Oil via an In Situ Generated Hybrid Peracids Mechanism

Mohamed Noorfazlida ; Chemical Engineering Studies, College of Engineering, Universiti Teknologi MARA, Cawangan Johor, Kampus Pasir Gudang, Malezija
Mohamad Zarqani Yeop ; Chemical Engineering Studies, College of Engineering, Universiti Teknologi MARA, Cawangan Johor, Kampus Pasir Gudang, Malezija
Intan Suhada Azmi orcid.org/0000-0002-1544-1939 ; Chemical Engineering Studies, College of Engineering, Universiti Teknologi MARA, Cawangan Johor, Kampus Pasir Gudang, Malezija
Siti Mariam A. Rahman ; MM Biomass Global Sdn. Bhd, Selangor, Malezija
Nur Izzah Anati Morsidi ; Chemical Engineering Studies, College of Engineering, Universiti Teknologi MARA, Cawangan Johor, Kampus Pasir Gudang, Malezija
Nursyazliana Kamal ; Chemical Engineering Studies, College of Engineering, Universiti Teknologi MARA, Cawangan Johor, Kampus Pasir Gudang, Malezija
Silvana Dwi Nurherdiana ; Low Carbon Technology Research Centre, Universitas Pembangunan Nasional Veteran Jawa Timur, Jl. Rungkut Madya No.1, Mt. Anyar, Gunung Anyar District, Surabaya 60294, East Java, Indonezija
Mohd Jumain Jalil ; Chemical Engineering Studies, College of Engineering, Universiti Teknologi MARA, Cawangan Johor, Kampus Pasir Gudang, Malezija *

* Dopisni autor.

Puni tekst: engleski pdf 412 Kb

str. 203-208

preuzimanja: 257

citiraj

APA 6th Edition

Noorfazlida, M., Yeop, M.Z., Azmi, I.S., Rahman, S., Morsidi, N.I.A., Kamal, N., ... Jalil, M.J. (2025). Catalytic Epoxidation of Rice Bran Oil via an In Situ Generated Hybrid Peracids Mechanism. Kemija u industriji, 74 (5-6), 203-208. https://doi.org/10.15255/KUI.2024.045

MLA 8th Edition

Noorfazlida, Mohamed, et al. "Catalytic Epoxidation of Rice Bran Oil via an In Situ Generated Hybrid Peracids Mechanism." Kemija u industriji, vol. 74, br. 5-6, 2025, str. 203-208. https://doi.org/10.15255/KUI.2024.045. Citirano 24.05.2026.

Chicago 17th Edition

Noorfazlida, Mohamed, Mohamad Zarqani Yeop, Intan Suhada Azmi, Siti Mariam A. Rahman, Nur Izzah Anati Morsidi, Nursyazliana Kamal, Silvana Dwi Nurherdiana i Mohd Jumain Jalil. "Catalytic Epoxidation of Rice Bran Oil via an In Situ Generated Hybrid Peracids Mechanism." Kemija u industriji 74, br. 5-6 (2025): 203-208. https://doi.org/10.15255/KUI.2024.045

Harvard

Noorfazlida, M., et al. (2025). 'Catalytic Epoxidation of Rice Bran Oil via an In Situ Generated Hybrid Peracids Mechanism', Kemija u industriji, 74(5-6), str. 203-208. https://doi.org/10.15255/KUI.2024.045

Vancouver

Noorfazlida M, Yeop MZ, Azmi IS, Rahman S, Morsidi NIA, Kamal N i sur. Catalytic Epoxidation of Rice Bran Oil via an In Situ Generated Hybrid Peracids Mechanism. Kemija u industriji [Internet]. 2025 [pristupljeno 24.05.2026.];74(5-6):203-208. https://doi.org/10.15255/KUI.2024.045

IEEE

M. Noorfazlida, et al., "Catalytic Epoxidation of Rice Bran Oil via an In Situ Generated Hybrid Peracids Mechanism", Kemija u industriji, vol.74, br. 5-6, str. 203-208, 2025. [Online]. https://doi.org/10.15255/KUI.2024.045

Sažetak

In this study, in-situ formed peracid was used to generate epoxidised rice bran oil. The following were found to be the ideal epoxidation reaction parameters: (1) 85 °C reaction temperature; (2) 0.8 g catalyst loading hybrid oxygen carrier; (3) 450 rpm string speed; and (4) 1.1 molar ratio of hydrogen peroxide to rice bran oil. Under these conditions, the highest oxirane content achieved was 49 %. A mathematical model was developed in MATLAB using the fourth-order Runge-Kutta method and simulated annealing optimisation to describe the reaction’s kinetic behaviour accurately. By turning rice bran oil into a product with added value, this study helps reduce dependency on petroleum-based resources and offers important insights into reaction dynamics, which are crucial for industrial applications.