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https://doi.org/10.5599/jese.3077

Parameter selection of cerium oxide anodic electrodeposition on screen-printed carbon electrodes using response surface methodology for nucleic acid based biosensors

Clianta Yudin Kharismasari ; Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Padjadjaran, Bandung 45363, Indonesia
Ari Hardianto ; Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Padjadjaran, Bandung 45363, Indonesia and Study Center of Sensor and Green Chemistry, Faculty of Mathematics and Natural Science, Universitas Padjadjaran, Bandung 40132, Indonesia
Muhammad Ihda Hamlu Liwaissunati Zein ; Department of Chemistry “Giacomo Ciamician”, Alma Mater Studiorum - University of Bologna, Bologna 40126, Italy
Salma Nur Zakiyyah orcid id orcid.org/0000-0003-0985-5980 ; Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Padjadjaran, Bandung 45363, Indonesia
Yeni Wahyuni Hartati ; Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Padjadjaran, Bandung 45363, Indonesia and Study Center of Sensor and Green Chemistry, Faculty of Mathematics and Natural Science, Universitas Padjadjaran, Bandung 40132, Indonesia
Irkham Irkham ; Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Padjadjaran, Bandung 45363, Indonesia *

* Dopisni autor.


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Sažetak

Screen-printed carbon electrodes (SPCEs) modified with cerium oxide (ceria) have attracted considerable attention due to their outstanding stability and electrochemical performance, making them promising candidates for sensor and biosensor applications. However, the anodic electrodeposition of ceria on SPCEs involves multiple parameters that may strongly influence film formation and electrochemical behaviour, yet these factors have not been systematically optimized. This study aimed to determine and optimize the key parameters affecting anodic electrodeposition of ceria on SPCEs using cyclic voltammetry (CV) and res­ponse surface methodology. All four main parameters, namely UV irradiation time, distance between the SPCE and UV lamp, cerium nitrate concentration and the number of CV cycles, significantly influence the anodic electrodeposition process of ceria, shown by the statistical analysis (p

Ključne riječi

Ceria layer; parameter optimization; RNA immobilization; guanine oxidation

Hrčak ID:

346201

URI

https://hrcak.srce.hr/346201

Datum izdavanja:

30.3.2026.

Posjeta: 47 *