Original scientific paper

The Crystal Structure of Di-pyridino-mercuric Chloride

D. Grdenić ; Laboratory for General and Inorganic Chemistry, Faculty of Science, University of Zagreb, Zagreb, Croatia, Yugoslavia
I. Krstanović ; Laboratory for General and Inorganic Chemistry, Faculty of Science, University of Zagreb, Zagreb, Croatia, Yugoslavia

Abstract

Di-pyridino-mercuric chloride HgCl2 . 2CsHsN crystallizes in the space group C 5/2h - P2 1/a with the cell dimensions: a = 17.70A b = 8.62A c = 3.90A B = 93 with two formula units in the cell.
The structure was solved by means of the two-dimensional [001] Fourier-Bragg projection. Each mercury atom is surrounded by two nearer chlorine atoms at a distance of 2.34 A, two farther chlorine atoms at a distance of 3.25 A and two nitrogen atoms at a distance of 2.60 A in a deformed octahedral coordination.

Keywords

Hrčak ID:

247918

URI

https://hrcak.srce.hr/247918

Publication date:

1.11.1955.

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