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https://doi.org/10.5562/cca1828

Bimetallic Copper-Heme-Protein-DNA Hybrid Catalyst for Diels Alder Reaction

Chi-Hsien Kuo ; Technische Universität Dortmund, Fakultät Chemie, Biologisch-Chemische Mikrostrukturtechnik, Otto-Hahn Str. 6, D-44227 Dortmund; Germany; Institute of Chemistry, Academia Sinica, 128 Academia Road Scc. 2, Nankang, Taipei 11529, Taiwan
Christof M Niemeyer ; Technische Universität Dortmund, Fakultät Chemie, Biologisch-Chemische Mikrostrukturtechnik, Otto-Hahn Str. 6, D-44227 Dortmund, Germany
Ljiljana Fruk ; DFG-Centre For Functional Nanostructures, Karlsruhe Institute of Technology, Wolfgang Gaede Str. 1a, 76131 Karlsruhe, Germany

Puni tekst: engleski, pdf (6 MB) str. 269-275 preuzimanja: 1.049* citiraj
APA 6th Edition
Kuo, C., Niemeyer, C.M. i Fruk, Lj. (2011). Bimetallic Copper-Heme-Protein-DNA Hybrid Catalyst for Diels Alder Reaction. Croatica Chemica Acta, 84 (2), 269-275. https://doi.org/10.5562/cca1828
MLA 8th Edition
Kuo, Chi-Hsien, et al. "Bimetallic Copper-Heme-Protein-DNA Hybrid Catalyst for Diels Alder Reaction." Croatica Chemica Acta, vol. 84, br. 2, 2011, str. 269-275. https://doi.org/10.5562/cca1828. Citirano 11.04.2021.
Chicago 17th Edition
Kuo, Chi-Hsien, Christof M Niemeyer i Ljiljana Fruk. "Bimetallic Copper-Heme-Protein-DNA Hybrid Catalyst for Diels Alder Reaction." Croatica Chemica Acta 84, br. 2 (2011): 269-275. https://doi.org/10.5562/cca1828
Harvard
Kuo, C., Niemeyer, C.M., i Fruk, Lj. (2011). 'Bimetallic Copper-Heme-Protein-DNA Hybrid Catalyst for Diels Alder Reaction', Croatica Chemica Acta, 84(2), str. 269-275. https://doi.org/10.5562/cca1828
Vancouver
Kuo C, Niemeyer CM, Fruk Lj. Bimetallic Copper-Heme-Protein-DNA Hybrid Catalyst for Diels Alder Reaction. Croatica Chemica Acta [Internet]. 2011 [pristupljeno 11.04.2021.];84(2):269-275. https://doi.org/10.5562/cca1828
IEEE
C. Kuo, C.M. Niemeyer i Lj. Fruk, "Bimetallic Copper-Heme-Protein-DNA Hybrid Catalyst for Diels Alder Reaction", Croatica Chemica Acta, vol.84, br. 2, str. 269-275, 2011. [Online]. https://doi.org/10.5562/cca1828

Sažetak
A bimetallic heme-DNA cofactor, containing an iron and a copper center, was synthesized for
the design of novel hybrid catalysts for stereoselective synthesis. The cofactor was used for the
reconstitution of apo-myoglobin. Both the cofactor alone and its myoglobin adduct were used to catalyze
a model Diels Alder reaction. Stereoselectivity of this conversion was analyzed by chiral HPLC.
Reactions carried out in the presence of myoglobin-heme-Cu-DNA catalyst showed greater product
conversion and stereoselectivity than those carried out with the heme-Cu-DNA cofactor. This observation
suggested that the protein shell plays a significant role in the catalytic conversion.(doi: 10.5562/cca1828)

Ključne riječi
bioorganic chemistry; DNA-protein conjugates; stereoselective catalysis

Hrčak ID: 71990

URI
https://hrcak.srce.hr/71990

Posjeta: 1.369 *