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Original scientific paper

On a Possible Role of Dicarboxylate Ions in the Formation of Open-framework Metallophosphates

Nevenka Rajić
Nataša Zabukovec Logar
Gregor Mali
Djordje Stojaković
Venčeslav Kaučoč

Fulltext: english, pdf (454 KB) pages 187-193 downloads: 575* cite
APA 6th Edition
Rajić, N., Zabukovec Logar, N., Mali, G., Stojaković, D. & Kaučoč, V. (2006). On a Possible Role of Dicarboxylate Ions in the Formation of Open-framework Metallophosphates. Croatica Chemica Acta, 79 (2), 187-193. Retrieved from https://hrcak.srce.hr/4123
MLA 8th Edition
Rajić, Nevenka, et al. "On a Possible Role of Dicarboxylate Ions in the Formation of Open-framework Metallophosphates." Croatica Chemica Acta, vol. 79, no. 2, 2006, pp. 187-193. https://hrcak.srce.hr/4123. Accessed 7 Jun. 2020.
Chicago 17th Edition
Rajić, Nevenka, Nataša Zabukovec Logar, Gregor Mali, Djordje Stojaković and Venčeslav Kaučoč. "On a Possible Role of Dicarboxylate Ions in the Formation of Open-framework Metallophosphates." Croatica Chemica Acta 79, no. 2 (2006): 187-193. https://hrcak.srce.hr/4123
Harvard
Rajić, N., et al. (2006). 'On a Possible Role of Dicarboxylate Ions in the Formation of Open-framework Metallophosphates', Croatica Chemica Acta, 79(2), pp. 187-193. Available at: https://hrcak.srce.hr/4123 (Accessed 07 June 2020)
Vancouver
Rajić N, Zabukovec Logar N, Mali G, Stojaković D, Kaučoč V. On a Possible Role of Dicarboxylate Ions in the Formation of Open-framework Metallophosphates. Croatica Chemica Acta [Internet]. 2006 [cited 2020 June 07];79(2):187-193. Available from: https://hrcak.srce.hr/4123
IEEE
N. Rajić, N. Zabukovec Logar, G. Mali, D. Stojaković and V. Kaučoč, "On a Possible Role of Dicarboxylate Ions in the Formation of Open-framework Metallophosphates", Croatica Chemica Acta, vol.79, no. 2, pp. 187-193, 2006. [Online]. Available: https://hrcak.srce.hr/4123. [Accessed: 07 June 2020]

Abstracts
Three dicarboxylic acids (oxalic, malonic and terephthalic) were investigated as possible pillars in the formation of metallophosphates with extended structures in the presence of 1,2-diaminopropane (DAP) as a structure-directing agent. Only the oxalate ion was proven to be a suitable building block in the formation of hybrid networks. The terephthalate ion seems to possess the ability to be structurally involved in lattice formation, although not in networks of the hybrid type. The malonate ion in this system showed no propensity towards lattice formation, i.e., malonic acid merely exits as an intercalated species inside the 2–D zincophosphate structure. Different pillar-functioning ability has been attributed to structural differences of the
three dicarboxylate ions.

Keywords
open-framework: inorganic-organic hybrid; template; dicarboxylate; porous; hydrothermal synthesis

Hrčak ID: 4123

URI
https://hrcak.srce.hr/4123

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