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https://doi.org/10.13044/j.sdewes.2016.04.0023

Migration Behaviour of Strontium in Czech Bentonite Clay

Lucie Baborová ; Department of Nuclear Chemistry, Faculty of Nuclear Sciences and Physical Engineering, Czech Technical University in Prague, Břehová 7, 115 19 Prague, Czech Republic
Dušan Vopálka ; Department of Nuclear Chemistry, Faculty of Nuclear Sciences and Physical Engineering, Czech Technical University in Prague, Břehová 7, 115 19 Prague, Czech Republic
Aleš Vetešník ; Department of Nuclear Chemistry, Faculty of Nuclear Sciences and Physical Engineering, Czech Technical University in Prague, Břehová 7, 115 19 Prague, Czech Republic
Eva Hofmanová ; Department of Nuclear Chemistry, Faculty of Nuclear Sciences and Physical Engineering, Czech Technical University in Prague, Břehová 7, 115 19 Prague, Czech Republic


Puni tekst: engleski pdf 866 Kb

str. 293-306

preuzimanja: 430

citiraj


Sažetak

The study deals with sorption and diffusion behaviour of strontium in Czech bentonite B75. The study is a part of a research on reactive transport of radioactive contaminants in barrier materials of a deep geological repository of radioactive waste in the Czech Republic. Series of sorption and diffusion experiments with Sr and non-activated Ca bentonite B75 produced in the Czech Republic were performed in two background solutions (CaCl2 and NaCl). On the basis of sorption batch experiments the kinetics of strontium sorption on bentonite was assessed and the sorption isotherms for various experimental conditions were obtained. As a result of performed diffusion experiments the parameters of diffusion (i.e. effective diffusion coefficient De and apparent diffusion coefficient Da) were determined. The observed discrepancies between sorption characteristics obtained from the sorption and diffusion experiments are discussed.

Ključne riječi

Bentonite, Strontium, Radionuclide migration, Reactive transport, Diffusion experiments, Batch method

Hrčak ID:

163380

URI

https://hrcak.srce.hr/163380

Posjeta: 875 *