Review article
https://doi.org/10.15255/KUI.2020.020
The Application of Headspace Solid-phase Microextraction as a Preparation Approach for Gas Chromatography with Mass Spectrometry
Igor Jerković
; University of Split, Faculty of Chemistry and Technology, Department of Organic Chemistry, R. Boškovića 35, 21 000 Split, Croatia
Zvonimir Marijanović
orcid.org/0000-0001-9786-5956
; University of Split, Faculty of Chemistry and Technology, Department of Food Technology and Biotechnology, R. Boškovića 35, 21 000 Split, Croatia
Ani Radonić
orcid.org/0000-0003-2744-9441
; University of Split, Faculty of Chemistry and Technology, Department of Food Technology and Biotechnology, R. Boškovića 35, 21 000 Split, Croatia
Marina Zekić
; University of Split, Faculty of Chemistry and Technology, Department of Organic Chemistry, R. Boškovića 35, 21 000 Split, Croatia
Marina Kranjac
orcid.org/0000-0001-8567-9742
; University of Split, Faculty of Chemistry and Technology, Department of Organic Chemistry, R. Boškovića 35, 21 000 Split, Croatia
Abstract
Reviewed in brief are the selected results of the application of headspace solid-phase microextraction as a preparative approach for gas chromatography – mass spectrometry (HS-SPME/GC-MS) for natural organic compounds research at the University of Split, Faculty of Chemistry and Technology. A wide variety of headspace compounds from different natural sources has been identified: lower aliphatic compounds (e.g., C5- and C6-compounds), aromatic compounds, monoterpenes (e.g., linalool derivatives (oxides, anhydro-oxides, epoxides), hotrienol), sesquiterpenes (e.g., eudesmol isomers, hydrocarbons), and C9- and C13-norisoprenoids (e.g., 3,4-dihydro-3-oxoedulan, 4-oxoisophorone, trans-β-damascenone). These compounds are important phytochemicals as flavour/fragrance compounds, chemical markers of the botanical origin or others (e.g., allelochemicals, pheromones, or acaricide residue).
This work is licensed under a Creative Commons Attribution 4.0 International License.
Keywords
headspace solid-phase microextraction (HS-SPME); gas chromatography and mass spectrometry (GC-MS); lower aliphatic compounds; aromatic compounds; monoterpenes; sesquiterpenes; C9- and C13-norisoprenoids
Hrčak ID:
243912
URI
Publication date:
24.9.2020.
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