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Ligand Field Splitting of d-Orbitals in Eight Coordinated Complexes of Square Antiprism Structure

M. Randić ; Department of Physical Chemistry Institute Ruder Boskovic, Zagreb, Croatia,Yugoslavia

Puni tekst: engleski, pdf (3 MB) str. 189-192 preuzimanja: 240* citiraj
APA 6th Edition
Randić, M. (1960). Ligand Field Splitting of d-Orbitals in Eight Coordinated Complexes of Square Antiprism Structure. Croatica Chemica Acta, 32 (4), 189-192. Preuzeto s https://hrcak.srce.hr/208591
MLA 8th Edition
Randić, M.. "Ligand Field Splitting of d-Orbitals in Eight Coordinated Complexes of Square Antiprism Structure." Croatica Chemica Acta, vol. 32, br. 4, 1960, str. 189-192. https://hrcak.srce.hr/208591. Citirano 06.03.2021.
Chicago 17th Edition
Randić, M.. "Ligand Field Splitting of d-Orbitals in Eight Coordinated Complexes of Square Antiprism Structure." Croatica Chemica Acta 32, br. 4 (1960): 189-192. https://hrcak.srce.hr/208591
Harvard
Randić, M. (1960). 'Ligand Field Splitting of d-Orbitals in Eight Coordinated Complexes of Square Antiprism Structure', Croatica Chemica Acta, 32(4), str. 189-192. Preuzeto s: https://hrcak.srce.hr/208591 (Datum pristupa: 06.03.2021.)
Vancouver
Randić M. Ligand Field Splitting of d-Orbitals in Eight Coordinated Complexes of Square Antiprism Structure. Croatica Chemica Acta [Internet]. 1960 [pristupljeno 06.03.2021.];32(4):189-192. Dostupno na: https://hrcak.srce.hr/208591
IEEE
M. Randić, "Ligand Field Splitting of d-Orbitals in Eight Coordinated Complexes of Square Antiprism Structure", Croatica Chemica Acta, vol.32, br. 4, str. 189-192, 1960. [Online]. Dostupno na: https://hrcak.srce.hr/208591. [Citirano: 06.03.2021.]

Sažetak
The spliUing of d-orbitals in the ligand field of a square antiprism
structure is given. Fivefold degenerate level splits into
A1 + E2+ E 3. The energy order of d orbitals is obtained from known
order of d orbitals in a cube considering the effect of distortion
of a cube into an antiprism on each of d orbitals. It foll ows that
dz2 orbital is substantially more stable than others.

Hrčak ID: 208591

URI
https://hrcak.srce.hr/208591

Posjeta: 289 *