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Croatica Chemica Acta , Vol. 65 No. 3, 1992.

  • Publication date: 15.10.1992.
  • Published on HRČAK: 09.04.2015.

Table of contents

Full text

Participation in Solvolysis: A Look Back (page 489-504)

William J. le Noble
Review article


The Contribution of Tunneling to Secondary Isotope Effects (page 505-515)

William H. Saunders, Jr.
Original scientific paper


Solvolysis of 1-(3-Noradamantyl)-2-methylpropyl and 1-(3-Noradamantyl)-2,2-dimethylpropyl Pemsylates (page 517-538)

D. T. Stoelting, V. J. Shiner, Jr.
Original scientific paper


The Nature of Nucleophilic Assistance to Ion-Pair Formation. Solvolyses of Cyclohexyl p-Toluenesulfonate (page 539-546)

Dennis N. Kevill, Mohamad H. Abduljaber
Original scientific paper


Solvolysis Kinetics of 1-Chloro-1-phenyl-5,9,14,18,22-pentamethyl-5,9,13,17,21-tricosapentaene, a Squalene Derivative. Indication of Participation (page 547-549)

Ivica Malnar, Olga Kronja, Krešimir Humski, Stanko Borčić
Preliminary communication


Approaches to Destabilized 7-Norbornyl Cations (page 551-566)

Wolfgang Kirmse, Sabine Schoen
Original scientific paper


Rates and Mechanism of Solvolysis of Arenediazonium Ions in Aqueous Trifluoroethanol (page 567-574)

H. Maskill, Katharine McCrudden
Original scientific paper


Similarity Models for Solvation Effects on Reactivity. The Dissociative Reaction Channel for Solvolyses of Sulphonyl Chlorides in Binary Aqueous Mixtures (page 575-583)

T. William Bentley, In Sun Koo, Gareth Llewellyn, Simon J. Norman
Original scientific paper


On a New Mechanism of S-O Scission in the Solvolysis of Aryl Triflates (page 585-592)

Takaaki Sonoda, Antonio Garcia Martinez, Michael Hanack, L. R. Subramanian
Original scientific paper


Carbocations from Arene Hydrates and Arene Oxides (page 593-614)

Rory A. More O’Ferrall, S. Nagaraja Rao
Review article


What is a Good Approximation for the Transition State of an SN2 Reaction? (page 625-631)

Addy Pross, Sason Shaik
Original scientific paper


Calculations on Fluorine Bridged Carbocations (page 633-653)

Michael A. McAllister, Thomas T. Tidwell
Original scientific paper


The C3H7+ Cation (page 655-672)

Wolfram Koch, Paul von Rague Schleyer, Peter Buzek, Bowen Liu
Original scientific paper


Deuterium and Carbon-13 Scrambling Processes in Isopropyl Cation (page 673-678)

Martin Saunders, Alan P. Hewett, Olga Kronja
Original scientific paper


Deuterium Isotope Effects on the Carbon-13 Chemical Shifts in 2-Substituted-2-Norbornyl Cations (page 679-701)

Kenneth L. Servis, Edward V. Koh, Peter Baine
Original scientific paper


NMR Isotope Shift Evidence for Conformational Structures of Dimethyl-9,10-Dihydroanthracenes and the 1,4,4-Trimethylcyclohexyl Cation (page 703-711)

David A. Forsyth, Adel M. Moussa, Chitchanun Panyachotipun
Original scientific paper


Non-degenerate Exchange of 1,2-Dialkyl Groups in Naphthalenium Cations (page 713-720)

David P. Kelly, Alicia M. Dachs, Voon Y. Stokie
Original scientific paper


NMR/IGLO/Ab initio Study of the 1,3-Dithiolanium Cation (page 721-725)

George A. Olah, V. Prakash Reddy, Golam Rasul, G. K. Surya Prakash
Original scientific paper


Crystal Structure Analysis and NMR Spectra of N-(Pentafluorobenzoyl)-4-dimethylaminopyridinium Hexachloroantimonate(V) (page 727-736)

Sandro Hollenstein, Christian Lohse, Thomas Laube
Original scientific paper


Diallylic and Diallenic Dyotropic Rearrangements (page 737-743)

Joseph B. Lambert, Daniel Stec III
Original scientific paper


Study of a Sterically Hindered Enol to Ketone Rearrangement by Stopped-Flow Gas Chromatography (page 745-756)

Lena Swahn, Per Ahlberg, Zvi Rappoport
Original scientific paper


A Convenient Preparation of Organofluorosilanes. A Possible Involvement of Tetracoordinated Siliconium Ion Pairs (page 757-761)

Yitzhak Apeloig, Osnat Merin-Aharoni
Short communication, Note


Speciation of A 1-Alkyl-4-Cyanopyridinium Iodide Using the Charge Transfer Band (page 763-777)

David A. Binder, C. Allen Mead, Maurice M. Kreevoy
Original scientific paper


Reactive Intermediates and the Question of Concertedness in the Catalytic Power of Enzymes (page 779-788)

Richard L. Schowen, K. Barbara Schowen
Original scientific paper


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