Review article

https://doi.org/10.15255/KUI.2020.020

The Application of Headspace Solid-phase Microextraction as a Preparation Approach for Gas Chromatography with Mass Spectrometry

Igor Jerković ; University of Split, Faculty of Chemistry and Technology, Department of Organic Chemistry, R. Boškovića 35, 21 000 Split, Croatia
Zvonimir Marijanović orcid.org/0000-0001-9786-5956 ; University of Split, Faculty of Chemistry and Technology, Department of Food Technology and Biotechnology, R. Boškovića 35, 21 000 Split, Croatia
Ani Radonić orcid.org/0000-0003-2744-9441 ; University of Split, Faculty of Chemistry and Technology, Department of Food Technology and Biotechnology, R. Boškovića 35, 21 000 Split, Croatia
Marina Zekić ; University of Split, Faculty of Chemistry and Technology, Department of Organic Chemistry, R. Boškovića 35, 21 000 Split, Croatia
Marina Kranjac orcid.org/0000-0001-8567-9742 ; University of Split, Faculty of Chemistry and Technology, Department of Organic Chemistry, R. Boškovića 35, 21 000 Split, Croatia

Abstract

Reviewed in brief are the selected results of the application of headspace solid-phase microextraction as a preparative approach for gas chromatography – mass spectrometry (HS-SPME/GC-MS) for natural organic compounds research at the University of Split, Faculty of Chemistry and Technology. A wide variety of headspace compounds from different natural sources has been identified: lower aliphatic compounds (e.g., C₅- and C₆-compounds), aromatic compounds, monoterpenes (e.g., linalool derivatives (oxides, anhydro-oxides, epoxides), hotrienol), sesquiterpenes (e.g., eudesmol isomers, hydrocarbons), and C₉- and C₁₃-norisoprenoids (e.g., 3,4-dihydro-3-oxoedulan, 4-oxoisophorone, trans-β-damascenone). These compounds are important phytochemicals as flavour/fragrance compounds, chemical markers of the botanical origin or others (e.g., allelochemicals, pheromones, or acaricide residue).




This work is licensed under a Creative Commons Attribution 4.0 International License.

Keywords

headspace solid-phase microextraction (HS-SPME); gas chromatography and mass spectrometry (GC-MS); lower aliphatic compounds; aromatic compounds; monoterpenes; sesquiterpenes; C9- and C13-norisoprenoids

Hrčak ID:

243912

URI

https://hrcak.srce.hr/243912

Publication date:

24.9.2020.

Article data in other languages: croatian

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